Characterization of Laser Doped Silicon and Overcoming Adhesion Challenges of Solar Cells with Nicke

Characterization of Laser Doped Silicon and Overcoming Adhesion Challenges of Solar Cells with Nicke
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ISBN: 9783839609163
Autor: Christian Geisler
Einband/Bindung: Taschenbuch
Sprache: Englisch
Seitenzahl: 175
Erscheinungsjahr: 2015
Verlag: Fraunhofer Verlag
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Beschreibung
The combination of localized laser patterning and metal plating allows to replace conventional silver screen printing with nickel-copper plating to form inexpensive front contacts for crystalline silicon solar cells. In this work, a focus is put on effects that could cause inhomogeneous metal deposition and low metal contact adhesion. A descriptive model of the silicon nitride ablation mechanism is derived from SEM imaging and a precise recombination analysis using QSSPC measurements. Surface sensitive XPS measurements are conducted to prove the existence of a parasitic surface layer, identified as SiOxNy. The dense SiOxNy layer is an effective diffusion barrier, hindering the formation of a nickel silicide interlayer. After removal of the SiOxNy layer, cells show severe degradation caused by metal-induced shunting. These shunts are imaged using reverse biased electroluminescence imaging. A shunting mechanism is proposed and experimentally verified. New laser process sequences are devised and proven to produce cells with adhering Ni-Cu contacts. Conclusively the developed processes are assessed based on their industrial feasibility as well as on their efficiency potential.
Artikel-Nr.: 9783839609163
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